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Simulation of the Weathering of Gasolines Using Gas Chromotographic Retention Data

NCJ Number
133231
Journal
Journal of the Forensic Science Society Volume: 31 Issue: 3 Dated: (July-September 1991) Pages: 309-319
Author(s)
R Hirz; A M Rizzi
Date Published
1991
Length
11 pages
Annotation
A method of calculation based on a simple equation derived from batch distillation theory is evaluated.
Abstract
This accounts for the evaporation loss of volatile components during the weathering of inflammable liquids. The relative volatility data required for the calculation are obtained from the capacity factors of the components in the gas chromatographic analysis. Starting from the gas chromatogram of a weathered sample of a gasoline, the chromatogram of the purported source sample is simulated. Generally, concentration patterns of residue samples can be correlated with those of reference samples, providing the evaporation loss has not exceeded 30 percent. This procedure could allow the tracing back of liquid samples from an arson scene to samples found in the possession of a suspect. 2 figures, 1 table, 20 notes, and 1 appendix (Author abstract)

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